We are able to clearly distinguish the processes responsible for enhanced low-intensity atomic Kerr nonlinearity, namely coherent population trapping and coherent population oscillations in experiments performed on the Rb D1 line, where one or the other process dominates under appropriate conditions. The potential of this approach based on wave mixing for probing coherent atomic media is discussed. It allows the new spectral components to be detected with sub-kHz resolution, which is well below the laser linewidth limit. Spatial selectivity and enhanced sensitivity make this method useful for testing dilute cold atomic samples.