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Response to 'Comment on 'Equations of state for fluids: the Dieterici approach revisited''

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posted on 2024-07-12, 23:31 authored by Richard SadusRichard Sadus
A re-evaluation is reported of earlier calculations for vapor–liquid equilibria [R. J. Sadus, J. Chem. Phys. 115, 1460(E) (2001); 116, 5913 (2202)] using the Dieterici–Carnahan–Starling (DCS) equation of state. The results for liquid-phase densities and properties near the critical point are generally consistent with the original work. However, the recalculated vapor-phase densities and coexistence pressures are shifted to substantially higher values. The implications for real fluids are that the DCS equation is likely to yield accurate predictions of both near-critical equilibria and the temperature-density behavior of the liquid phase at the expense of poor agreement with experiment for both vapor densities and pressures.

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ISSN

0021-9606

Journal title

Journal of Chemical Physics

Volume

120

Issue

18

Pagination

8870-8870

Publisher

American Institute of Physics

Copyright statement

Copyright © 2004 American Institute of Physics. is reproduced in accordance with the copyright policy of the publisher.

Language

eng

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